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Effect of H2S treatment on properties of CuInS2 thin films deposited by chemical spray pyrolysis at low temperature

Identifieur interne : 003157 ( Main/Repository ); précédent : 003156; suivant : 003158

Effect of H2S treatment on properties of CuInS2 thin films deposited by chemical spray pyrolysis at low temperature

Auteurs : RBID : Pascal:11-0433222

Descripteurs français

English descriptors

Abstract

CuInS2 thin films were deposited by chemical spray of aqueous solutions containing CuCl2, InCl3 and thiourea at substrate temperature of 250 °C in air and subjected to annealing at 530 °C in H2S atmosphere. Structure and composition before and after annealing were studied by XRD, EDS, XPS and Raman spectroscopy. As-sprayed films were low-crystalline, showed uniform distribution of elements in film thickness and no oxygen content. For the CuInS2 films deposited from the solutions with [Cu2+]/[In3+] = 1.0 and 1.1, H2S treatment for 30 min increased the chalcopyrite content up to 73% and 51%, respectively. CuxS phase in sprayed CIS films promotes the crystallite growth but retards the formation of chalcopyrite phase during H2S treatment.

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Pascal:11-0433222

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<title xml:lang="en" level="a">Effect of H2S treatment on properties of CuInS2 thin films deposited by chemical spray pyrolysis at low temperature</title>
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<name sortKey="K Rber, E" uniqKey="K Rber E">E. K Rber</name>
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<s1>Department of Materials Science, Tallinn University of Technology, Ehitajate tee 5</s1>
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<name sortKey="Katerski, A" uniqKey="Katerski A">A. Katerski</name>
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<s1>Department of Materials Science, Tallinn University of Technology, Ehitajate tee 5</s1>
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<name sortKey="Mere, A" uniqKey="Mere A">A. Mere</name>
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<s1>Department of Materials Science, Tallinn University of Technology, Ehitajate tee 5</s1>
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<author>
<name sortKey="Krunks, M" uniqKey="Krunks M">M. Krunks</name>
<affiliation wicri:level="1">
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<s1>Department of Materials Science, Tallinn University of Technology, Ehitajate tee 5</s1>
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<idno type="inist">11-0433222</idno>
<date when="2011">2011</date>
<idno type="stanalyst">PASCAL 11-0433222 INIST</idno>
<idno type="RBID">Pascal:11-0433222</idno>
<idno type="wicri:Area/Main/Corpus">002835</idno>
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<seriesStmt>
<idno type="ISSN">0040-6090</idno>
<title level="j" type="abbreviated">Thin solid films</title>
<title level="j" type="main">Thin solid films</title>
</seriesStmt>
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<keywords scheme="KwdEn" xml:lang="en">
<term>Annealing</term>
<term>Aqueous solution</term>
<term>Chalcopyrite</term>
<term>Copper chloride</term>
<term>Copper sulfide</term>
<term>Crystallites</term>
<term>Dispersive spectrometry</term>
<term>Growth mechanism</term>
<term>Heat treatment</term>
<term>Hydrogen sulfides</term>
<term>Indium chloride</term>
<term>Indium sulfide</term>
<term>Layer thickness</term>
<term>Pyrolysis</term>
<term>Raman spectrometry</term>
<term>Solar cell</term>
<term>Thin film</term>
<term>Thiourea</term>
<term>Thioureas</term>
<term>X ray diffraction</term>
<term>X-ray photoelectron spectra</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Sulfure d'hydrogène</term>
<term>Cellule solaire</term>
<term>Couche mince</term>
<term>Pyrolyse</term>
<term>Solution aqueuse</term>
<term>Chlorure d'indium</term>
<term>Thiourées</term>
<term>Recuit</term>
<term>Diffraction RX</term>
<term>Spectrométrie dispersive</term>
<term>Spectre photoélectron RX</term>
<term>Spectrométrie Raman</term>
<term>Epaisseur couche</term>
<term>Cristallite</term>
<term>Sulfure de cuivre</term>
<term>Sulfure d'indium</term>
<term>Chlorure de cuivre</term>
<term>Thiourée</term>
<term>Chalcopyrite</term>
<term>Mécanisme croissance</term>
<term>Traitement thermique</term>
<term>CuInS2</term>
<term>InCl3</term>
<term>8460J</term>
<term>6855J</term>
<term>6855A</term>
<term>8115A</term>
</keywords>
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<front>
<div type="abstract" xml:lang="en">CuInS
<sub>2</sub>
thin films were deposited by chemical spray of aqueous solutions containing CuCl
<sub>2</sub>
, InCl
<sub>3</sub>
and thiourea at substrate temperature of 250 °C in air and subjected to annealing at 530 °C in H
<sub>2</sub>
S atmosphere. Structure and composition before and after annealing were studied by XRD, EDS, XPS and Raman spectroscopy. As-sprayed films were low-crystalline, showed uniform distribution of elements in film thickness and no oxygen content. For the CuInS
<sub>2</sub>
films deposited from the solutions with [Cu
<sup>2+</sup>
]/[In
<sup>3+</sup>
] = 1.0 and 1.1, H
<sub>2</sub>
S treatment for 30 min increased the chalcopyrite content up to 73% and 51%, respectively. Cu
<sub>x</sub>
S phase in sprayed CIS films promotes the crystallite growth but retards the formation of chalcopyrite phase during H
<sub>2</sub>
S treatment.</div>
</front>
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<fA05>
<s2>519</s2>
</fA05>
<fA06>
<s2>21</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG">
<s1>Effect of H2S treatment on properties of CuInS2 thin films deposited by chemical spray pyrolysis at low temperature</s1>
</fA08>
<fA09 i1="01" i2="1" l="ENG">
<s1>Proceedings of the EMRS 2010 Spring Meeting Symposium M: Thin Film Chalcogenide Photovoltaic Materials Strasbourg, France</s1>
</fA09>
<fA11 i1="01" i2="1">
<s1>KÄRBER (E.)</s1>
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<s1>KATERSKI (A.)</s1>
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<s1>MERE (A.)</s1>
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<s1>KRUNKS (M.)</s1>
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<fA12 i1="01" i2="1">
<s1>ROMEO (Alessandro)</s1>
<s9>ed.</s9>
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<s1>SCHEER (Roland)</s1>
<s9>ed.</s9>
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<s1>GUILLEMOLES (Jean François)</s1>
<s9>ed.</s9>
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<s1>YAMADA (Akira)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="05" i2="1">
<s1>ABOU-RAS (Daniel)</s1>
<s9>ed.</s9>
</fA12>
<fA14 i1="01">
<s1>Department of Materials Science, Tallinn University of Technology, Ehitajate tee 5</s1>
<s2>19086 Tallinn</s2>
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<s3>EST</s3>
<sZ>4 aut.</sZ>
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<fA18 i1="01" i2="1">
<s1>the European Materials Research Society (E-MRS</s1>
<s3>EUR</s3>
<s9>org-cong.</s9>
</fA18>
<fA20>
<s1>7180-7183</s1>
</fA20>
<fA21>
<s1>2011</s1>
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<fA23 i1="01">
<s0>ENG</s0>
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<fA43 i1="01">
<s1>INIST</s1>
<s2>13597</s2>
<s5>354000509101330130</s5>
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<fA44>
<s0>0000</s0>
<s1>© 2011 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45>
<s0>21 ref.</s0>
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<fA47 i1="01" i2="1">
<s0>11-0433222</s0>
</fA47>
<fA60>
<s1>P</s1>
<s2>C</s2>
</fA60>
<fA61>
<s0>A</s0>
</fA61>
<fA64 i1="01" i2="1">
<s0>Thin solid films</s0>
</fA64>
<fA66 i1="01">
<s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>CuInS
<sub>2</sub>
thin films were deposited by chemical spray of aqueous solutions containing CuCl
<sub>2</sub>
, InCl
<sub>3</sub>
and thiourea at substrate temperature of 250 °C in air and subjected to annealing at 530 °C in H
<sub>2</sub>
S atmosphere. Structure and composition before and after annealing were studied by XRD, EDS, XPS and Raman spectroscopy. As-sprayed films were low-crystalline, showed uniform distribution of elements in film thickness and no oxygen content. For the CuInS
<sub>2</sub>
films deposited from the solutions with [Cu
<sup>2+</sup>
]/[In
<sup>3+</sup>
] = 1.0 and 1.1, H
<sub>2</sub>
S treatment for 30 min increased the chalcopyrite content up to 73% and 51%, respectively. Cu
<sub>x</sub>
S phase in sprayed CIS films promotes the crystallite growth but retards the formation of chalcopyrite phase during H
<sub>2</sub>
S treatment.</s0>
</fC01>
<fC02 i1="01" i2="X">
<s0>001D06C02D1</s0>
</fC02>
<fC02 i1="02" i2="3">
<s0>001B60H55J</s0>
</fC02>
<fC02 i1="03" i2="3">
<s0>001B80A15A</s0>
</fC02>
<fC02 i1="04" i2="X">
<s0>230</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE">
<s0>Sulfure d'hydrogène</s0>
<s2>NK</s2>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG">
<s0>Hydrogen sulfides</s0>
<s2>NK</s2>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE">
<s0>Cellule solaire</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG">
<s0>Solar cell</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA">
<s0>Célula solar</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE">
<s0>Couche mince</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG">
<s0>Thin film</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA">
<s0>Capa fina</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Pyrolyse</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Pyrolysis</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Pirólisis</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Solution aqueuse</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Aqueous solution</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Solución acuosa</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Chlorure d'indium</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Indium chloride</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Indio cloruro</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Thiourées</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Thioureas</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Tioureas</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Recuit</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Annealing</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Recocido</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Diffraction RX</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>X ray diffraction</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Difracción RX</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Spectrométrie dispersive</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Dispersive spectrometry</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Espectrometría dispersiva</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Spectre photoélectron RX</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>X-ray photoelectron spectra</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Spectrométrie Raman</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Raman spectrometry</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Espectrometría Raman</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Epaisseur couche</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Layer thickness</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Espesor capa</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Cristallite</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Crystallites</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Cristalita</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Sulfure de cuivre</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG">
<s0>Copper sulfide</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA">
<s0>Cobre sulfuro</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Sulfure d'indium</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Indium sulfide</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Indio sulfuro</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>Chlorure de cuivre</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG">
<s0>Copper chloride</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA">
<s0>Cobre cloruro</s0>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE">
<s0>Thiourée</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG">
<s0>Thiourea</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA">
<s0>Tiourea</s0>
<s5>18</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE">
<s0>Chalcopyrite</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG">
<s0>Chalcopyrite</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA">
<s0>Calcopirita</s0>
<s5>19</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE">
<s0>Mécanisme croissance</s0>
<s5>29</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG">
<s0>Growth mechanism</s0>
<s5>29</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA">
<s0>Mecanismo crecimiento</s0>
<s5>29</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE">
<s0>Traitement thermique</s0>
<s5>30</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG">
<s0>Heat treatment</s0>
<s5>30</s5>
</fC03>
<fC03 i1="21" i2="X" l="SPA">
<s0>Tratamiento térmico</s0>
<s5>30</s5>
</fC03>
<fC03 i1="22" i2="X" l="FRE">
<s0>CuInS2</s0>
<s4>INC</s4>
<s5>46</s5>
</fC03>
<fC03 i1="23" i2="X" l="FRE">
<s0>InCl3</s0>
<s4>INC</s4>
<s5>47</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE">
<s0>8460J</s0>
<s4>INC</s4>
<s5>71</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE">
<s0>6855J</s0>
<s4>INC</s4>
<s5>72</s5>
</fC03>
<fC03 i1="26" i2="X" l="FRE">
<s0>6855A</s0>
<s4>INC</s4>
<s5>73</s5>
</fC03>
<fC03 i1="27" i2="X" l="FRE">
<s0>8115A</s0>
<s4>INC</s4>
<s5>74</s5>
</fC03>
<fN21>
<s1>297</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>EMRS Spring Meeting Symposium M: Thin Film Chalcogenide Photovoltaic Materials</s1>
<s2>10</s2>
<s3>Strasbourg FRA</s3>
<s4>2010-06-07</s4>
</fA30>
</pR>
</standard>
</inist>
</record>

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